By Boris Y. Zaslavsky
Covers the basic ideas of solute partitioning in aqueous two-phase platforms, explains their vital functional good points, and furnishes equipment of characterization. the knowledge supplied via the partition behaviour of a solute in an aqueous two-phase method is tested.
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Additional info for Aqueous Two-phase Partitioning
UsedIthe term "structure of water" It should be noted that up till now combining it with the "and/or thermodynamic state of water". The reason is books written on the subject, that in spite of the numerous papers, reviews, and the very basic questionsof how to define the "structure of water" and which experiment should be performed to measure the "structural changes" in water remain unanswered. as conceived by difThe ambiguity of the meaning of the above term ferent authors results in a wide-spread disagreement among investigators using different experimental techniques.
7) whichknown is to depend on the solution composition. The ionization potential of water molecule in liquid water appears to be a function of the water structureas follows from the aforementioned temperature dependence of pH of pure liquid water. Hence this parameter must as shown by the effects also depend on the composition of an aqueous medium of different additives on the basicity and acidity of the medium(seeabove). 6). Thus, it follows that the free energy of the solute-solvent interactions in an aqueous medium should depend on the composition of the medium.
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Aqueous Two-phase Partitioning by Boris Y. Zaslavsky