Download e-book for iPad: Catalysts for Fine Chemical Synthesis. Regio- and Stereo- by Stanley M. Roberts, John Whittall

By Stanley M. Roberts, John Whittall

ISBN-10: 0470090227

ISBN-13: 9780470090220

Quantity five within the Catalysts for high-quality Chemical Synthesis sequence describes new systems for the regio- and stereo-controlled variations of compounds regarding oxidation or aid reactions. It describes a variety of catalysts, together with organometallic platforms, biocatalysts and biomimetics. This quantity additionally comprises descriptions of quite a few conversions, together with: Baeyer-Villiger oxidations; Epoxidation reactions; Hydroxylation reactions; Oxidation of alcohols to aldehydes, ketones and carboxylic acids; relief of ketones; and aid of alkenes together with α, β-unsaturated carbonyl compounds. The ebook might be a massive textual content for practicing man made natural chemists in and academia.

  • Protocols are written in a regular layout by means of the authors who've chanced on them
  • Hints, counsel and security recommendation (where acceptable) is given to make sure that the techniques are reproducible
  • Indications are given as to the diversity of beginning fabrics used and, the place applicable, comparisons to replacement methodology
  • Includes appropriate references to the first literature.

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Extra info for Catalysts for Fine Chemical Synthesis. Regio- and Stereo- Controlled Oxidation and Reductions

Example text

Curr. Opin. Chem. Biol. 2004, 8, 120–126. 50. , Matsuda, T. and Harada, T. Recent Developments in Asymmetric Reduction of Ketones with Biocatalysts. Tetrahedron Asymmetry 2003, 14, 2659–2681. 32 REGIO- AND S TEREO-CONTRO LLED OXIDATIONS AND RE DUCTIONS 51. Zhao, H. A. Regeneration of Cofactors for use in Biocatalysis. Curr. Opin. Biotechnol. 2003, 14, 583–589. 52. Bommarius, A. -R. and Wandrey, C. Some New Developments in Reductive Amination with Cofactor Regeneration. Biocatalysis 1994, 10, 37–47.

Ed. 2006, 45, 4193–4195. 22. Adolfsson, H. Organocatalytic Hydride Transfers: A New Concept in Asymmetric Hydrogenations. Angew. Chem. Int. Ed. 2005, 44, 3340–3342. 23. -U. The Chiral Switch of (S)-Metolachlor: A Personal Account of an Industrial Odyssey in Asymmetric Catalysis. Adv. Synth. Catal. 2002, 344, 17–31. 24. , Ikariya, T. and Noyori, R. Practical Enantioselective Hydrogenation of Aromatic Ketones. J. Am. Chem. Soc. 1995, 117, 2675–2616. 25. , Inoue T. and Noyori, R. BINAP/1,4-DiamineRuthenium(II) Complexes for Efficient Asymmetric Hydrogenation of 1-Tetralones and Analogues.

Asymmetric Epoxidation via Phase-transfer Catalysis: Direct Conversion of Allylic Alcohols into a,b-Epoxyketones. Chem. Commun. 2002, 2360– 2361. 69. , Chen, J. and Liang, X. A Highly Enantioselective Phase-transfer Catalyzed Epoxidation of Enones with a mild Oxidant, Trichloroisocyanuric acid. Chem. Commun. 2003, 2714–2715. INDUSTRIAL CATALYSTS 33 70. , Ariga, M. and Tohda, Y. Asymmetric Epoxidation Catalyzed by Novel Azacrown Ether-type Chiral Quaternary Ammonium Salts under Phase-transfer Catalytic Conditions.

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Catalysts for Fine Chemical Synthesis. Regio- and Stereo- Controlled Oxidation and Reductions by Stanley M. Roberts, John Whittall

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