By Stanley M. Roberts, John Whittall
Quantity five within the Catalysts for high-quality Chemical Synthesis sequence describes new systems for the regio- and stereo-controlled variations of compounds regarding oxidation or aid reactions. It describes a variety of catalysts, together with organometallic platforms, biocatalysts and biomimetics. This quantity additionally comprises descriptions of quite a few conversions, together with: Baeyer-Villiger oxidations; Epoxidation reactions; Hydroxylation reactions; Oxidation of alcohols to aldehydes, ketones and carboxylic acids; relief of ketones; and aid of alkenes together with α, β-unsaturated carbonyl compounds. The ebook might be a massive textual content for practicing man made natural chemists in and academia.
- Protocols are written in a regular layout by means of the authors who've chanced on them
- Hints, counsel and security recommendation (where acceptable) is given to make sure that the techniques are reproducible
- Indications are given as to the diversity of beginning fabrics used and, the place applicable, comparisons to replacement methodology
- Includes appropriate references to the first literature.
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Extra info for Catalysts for Fine Chemical Synthesis. Regio- and Stereo- Controlled Oxidation and Reductions
Curr. Opin. Chem. Biol. 2004, 8, 120–126. 50. , Matsuda, T. and Harada, T. Recent Developments in Asymmetric Reduction of Ketones with Biocatalysts. Tetrahedron Asymmetry 2003, 14, 2659–2681. 32 REGIO- AND S TEREO-CONTRO LLED OXIDATIONS AND RE DUCTIONS 51. Zhao, H. A. Regeneration of Cofactors for use in Biocatalysis. Curr. Opin. Biotechnol. 2003, 14, 583–589. 52. Bommarius, A. -R. and Wandrey, C. Some New Developments in Reductive Amination with Cofactor Regeneration. Biocatalysis 1994, 10, 37–47.
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Asymmetric Epoxidation via Phase-transfer Catalysis: Direct Conversion of Allylic Alcohols into a,b-Epoxyketones. Chem. Commun. 2002, 2360– 2361. 69. , Chen, J. and Liang, X. A Highly Enantioselective Phase-transfer Catalyzed Epoxidation of Enones with a mild Oxidant, Trichloroisocyanuric acid. Chem. Commun. 2003, 2714–2715. INDUSTRIAL CATALYSTS 33 70. , Ariga, M. and Tohda, Y. Asymmetric Epoxidation Catalyzed by Novel Azacrown Ether-type Chiral Quaternary Ammonium Salts under Phase-transfer Catalytic Conditions.
Catalysts for Fine Chemical Synthesis. Regio- and Stereo- Controlled Oxidation and Reductions by Stanley M. Roberts, John Whittall