Read e-book online Electronic defect states in alkali halides : effects of PDF

By Volkmar Dierolf

ISBN-10: 3540004718

ISBN-13: 9783540004714

This updated textual content bargains with the mutual interplay and effort move among digital illness states of F centres and illness ions and neighbouring molecular defects in alkali halides. It comprises greater than a hundred illustrations and figures, plus many formerly unpublished results.

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This yields a correction factor n1 · EEeff for the absorption strength, in which the second term is usually approximated by the Lorenz-Lorentz factor: 1 2 4π 4π Eeff = αtotal = 1 + (N− α− + N+ α+ ) . 14) E 3 3 3 These expressions show that the correction has its origin in the sum αtotal of the atomic electronic polarizabilities α− and α+ of the N− and N+ anions and cations within the sample [18]. This method of simply adding up all contributions is certainly just an approximation, because at any given point within the lattice, the neighbors will be the most important.

D. Matteis, M. Leblans, W. Joosen, and D. Schoemaker, Phys. Rev. B 45, 10377 (1992). 47 K. Song, L. Chen, P. Tong, H. Yu, and C. Leung, J. : Condens. Matter 6, 5657 (1994). 47 L. Song and K. Song, Radiat. Eff. Defects Solids 134, 405 (1995). 47 5 FH(CN− ) Centers Among the electronic–molecular defect complexes the FH (CN− ) centers are the ones which have been studied in most detail (starting with the first observation of E–V transfer in 1983 [1, 2]) both experimentally1 and theoretically (as reviewed in Sect.

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Electronic defect states in alkali halides : effects of interaction with molecular ions by Volkmar Dierolf

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