By Norbert Auner, Johann Weis
Organosilicon Chemistry at its best... Like its highly profitable predecessor, this quantity provides the most recent advancements in a speedily constructing box of commercial and educational learn. Written through major specialists, it's a special guide for each scientist interested by organosilicon compounds and their purposes. From studies of the 1st quantity: 'The very good presentation of its contents promises that it'll occupy a in demand position in the literature on silicon chemistry.' Nachr. Chem. Lab. Techn. '... I do suggest this e-book hugely to these scientists in academia and who're energetic in molecular organosilicon chemistry and/or silicon-based fabrics science.' Synthesis
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Extra info for Organosilicon chemistry II: from molecules to materials
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Cunico, B. B. Chou, J. Organomet. Chem. 1978,154, C45; Damrauer, V. E. Yost, S. E. Danahey, B. K. OConnell, Organometallics 1985,4, 1779. Properties of Si-jiunctionalized (Fluoromethyijsilanes  29 J. A. Morrison, L. L. Gerchman, R. Eujen, R. J. Lagow, J. Fluorine Chem. 1977, 10, 333; H. Lange, D. Naumann, J. Fluorine Chem. 1985,27,115.  H. Beckers, H. Burger, P. Bursch, I. Ruppert, J. Organomet. Chem. 1986,316,41. [lo] H. Biirger, R. Eujen, P. Moritz, J. Organomet. Chem. 1991, 401,249. [I 11 K.
Therefore these appear to be particularly suited for gas phase investigations. The decrease of thermal stability of (fluoromethy1)silanes in comparison to the non-fluorinated methylsilanes is evident from their decomposition temperature under static conditions. This drops significantly in the series H3CSiH3 (2 340 "C), F3CSiH3, and F2HCSiH3(2 180 "C) to FH2CSiH3 (2 120 "C). While H3CSiH3decomposes under these conditions primarily by geminal elimination of molecular H2 from the silicon moiety and secondarily by a slow surface-catalysed reaction yielding Hand CH3SiH2*radicals , the significantly lower decomposition temperatures of (fluoromethy1)silanes require different low energy decomposition pathways.
Organosilicon chemistry II: from molecules to materials by Norbert Auner, Johann Weis